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Caesium fluoride-mediated hydrocarboxylation of alkenes and allenes: scope and mechanistic insights

A caesium fluoride-mediated hydrocarboxylation of olefins is disclosed that does not rely on precious transition metal catalysts and ligands. The reaction occurs at atmospheric pressures of CO(2) in the presence of 9-BBN as a stoichiometric reductant. Stilbenes, β-substituted styrenes and allenes co...

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Detalles Bibliográficos
Autores principales:	Gevorgyan, Ashot, Obst, Marc F., Guttormsen, Yngve, Maseras, Feliu, Hopmann, Kathrin H., Bayer, Annette
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6991174/ https://www.ncbi.nlm.nih.gov/pubmed/32055361 http://dx.doi.org/10.1039/c9sc02467k

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