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Rhodium(i)-catalyzed C6-selective C–H alkenylation and polyenylation of 2-pyridones with alkenyl and conjugated polyenyl carboxylic acids

A versatile Rh(i)-catalyzed C6-selective decarbonylative C–H alkenylation of 2-pyridones with readily available, and inexpensive alkenyl carboxylic acids has been developed. This directed dehydrogenative cross-coupling reaction affords 6-alkenylated 2-pyridones that would otherwise be difficult to a...

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Detalles Bibliográficos
Autores principales: Zhao, Haoqiang, Xu, Xin, Luo, Zhenli, Cao, Lei, Li, Bohan, Li, Huanrong, Xu, Lijin, Fan, Qinghua, Walsh, Patrick J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6991184/
https://www.ncbi.nlm.nih.gov/pubmed/32055363
http://dx.doi.org/10.1039/c9sc03672e