Influence of the distal guanidine group on the rate and selectivity of O(2) reduction by iron porphyrin

The O(2) reduction reaction (ORR) catalysed by iron porphyrins with covalently attached pendant guanidine groups is reported. The results show a clear enhancement in the rate and selectivity for the 4e(–)/4H(+) ORR. In situ resonance Raman investigations show that the rate determining step (rds) is...

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Detalles Bibliográficos
Autores principales: Ghatak, Arnab, Bhakta, Snehadri, Bhunia, Sarmistha, Dey, Abhishek
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6993607/
https://www.ncbi.nlm.nih.gov/pubmed/32055338
http://dx.doi.org/10.1039/c9sc02711d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6993607/
https://www.ncbi.nlm.nih.gov/pubmed/32055338
http://dx.doi.org/10.1039/c9sc02711d

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