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Design of non-ionic carbon superbases: second generation carbodiphosphoranes

A new generation of carbodiphosphoranes (CDPs), incorporating pyrrolidine, tetramethylguanidine, or tris(dimethylamino)phosphazene as substituents is introduced as the most powerful class of non-ionic carbon superbases on the basicity scale to date. The synthetic approach as well as NMR spectroscopi...

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Detalles Bibliográficos
Autores principales: Ullrich, Sebastian, Kovačević, Borislav, Koch, Björn, Harms, Klaus, Sundermeyer, Jörg
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6993619/
https://www.ncbi.nlm.nih.gov/pubmed/32055322
http://dx.doi.org/10.1039/c9sc03565f