Radical-mediated C-C cleavage of unstrained cycloketones and DFT study for unusual regioselectivity

The C-C σ-bond activation of unstrained cycloketones represents an ingenious and advanced technique in synthetic chemistry, but it remains a challenging area which has been largely underexplored. Herein we report an efficient strategy for the direct C-C cleavage of cyclohexanones and cyclopentanones...

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Detalles Bibliográficos
Autores principales: Wang, Mingyang, Li, Man, Yang, Shan, Xue, Xiao-Song, Wu, Xinxin, Zhu, Chen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6997357/
https://www.ncbi.nlm.nih.gov/pubmed/32015335
http://dx.doi.org/10.1038/s41467-020-14435-5

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6997357/
https://www.ncbi.nlm.nih.gov/pubmed/32015335
http://dx.doi.org/10.1038/s41467-020-14435-5

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