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Radical-mediated C-C cleavage of unstrained cycloketones and DFT study for unusual regioselectivity
The C-C σ-bond activation of unstrained cycloketones represents an ingenious and advanced technique in synthetic chemistry, but it remains a challenging area which has been largely underexplored. Herein we report an efficient strategy for the direct C-C cleavage of cyclohexanones and cyclopentanones...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6997357/ https://www.ncbi.nlm.nih.gov/pubmed/32015335 http://dx.doi.org/10.1038/s41467-020-14435-5 |