Cargando…

[Se(CH(2)C(O)CH(3))(3)][B(12)F(11)NH(3)]: The first selenium cation with three β-ketone substituents

The reaction of [Se(8)][B(12)F(11)NH(3)](2) with acetone and subsequent crystallization from acetone/diethyl ether yielded the selenium cation [Se(CH(2)C(O)CH(3))(3)](+) as a by-product, which is stabilized by the weakly coordinating undeca­fluorinated anion [B(12)F(11)NH(3)](−). While attempting to...

Descripción completa

Detalles Bibliográficos
Autores principales: Jenne, Carsten, Nierstenhöfer, Marc C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7001834/
https://www.ncbi.nlm.nih.gov/pubmed/32071750
http://dx.doi.org/10.1107/S2056989020000481