Cargando…
[Se(CH(2)C(O)CH(3))(3)][B(12)F(11)NH(3)]: The first selenium cation with three β-ketone substituents
The reaction of [Se(8)][B(12)F(11)NH(3)](2) with acetone and subsequent crystallization from acetone/diethyl ether yielded the selenium cation [Se(CH(2)C(O)CH(3))(3)](+) as a by-product, which is stabilized by the weakly coordinating undecafluorinated anion [B(12)F(11)NH(3)](−). While attempting to...
Autores principales: | , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2020
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7001834/ https://www.ncbi.nlm.nih.gov/pubmed/32071750 http://dx.doi.org/10.1107/S2056989020000481 |