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Synthesis and Reactivity of Cyclopentadienyl Ruthenium(II) Complexes with Tris(alkylthio)benzenes: Transformation between Dinuclear and Sandwich-Type Complexes

[Image: see text] To explore the structural transformation of cyclopentadienyl ruthenium (CpRu) complexes in response to external stimuli, the reaction of [RuCp(MeCN)(3)][X] (X = PF(6), (FSO(2))(2)N [= FSA]) and tris(alkylthio)benzenes (1,3,5-C(6)H(3)(SR)(3); L(1): R = Pr, L(2): R = Me) was investig...

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Detalles Bibliográficos
Autores principales: Fan, Rong, Sumitani, Ryo, Mochida, Tomoyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7003506/
https://www.ncbi.nlm.nih.gov/pubmed/32039341
http://dx.doi.org/10.1021/acsomega.9b04272