Stereospecific and Chemoselective Copper‐Catalyzed Deaminative Silylation of Benzylic Ammonium Triflates

A method for the synthesis of benzylsilanes starting from the corresponding ammonium triflates is reported. Silyl boronic esters are employed as silicon pronucleophiles, and the reaction is catalyzed by copper(I) salts. Enantioenriched benzylic ammonium salts react stereospecifically through an S(N)...

Descripción completa

Detalles Bibliográficos
Autores principales: Scharfbier, Jonas, Gross, Benjamin M., Oestreich, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7003868/
https://www.ncbi.nlm.nih.gov/pubmed/31730248
http://dx.doi.org/10.1002/anie.201912490

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7003868/
https://www.ncbi.nlm.nih.gov/pubmed/31730248
http://dx.doi.org/10.1002/anie.201912490

Ejemplares similares