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A Long‐Lived Azafullerenyl Radical Stabilized by Supramolecular Shielding with a [10]Cycloparaphenylene

A major handicap towards the exploitation of radicals is their inherent instability. In the paramagnetic azafullerenyl radical C(59)N(.), the unpaired electron is strongly localized next to the nitrogen atom, which induces dimerization to diamagnetic bis(azafullerene), (C(59)N)(2). Conventional stab...

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Detalles Bibliográficos
Autores principales: Stergiou, Anastasios, Rio, Jérémy, Griwatz, Jan H., Arčon, Denis, Wegner, Hermann A., Ewels, Christopher P., Tagmatarchis, Nikos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7003913/
https://www.ncbi.nlm.nih.gov/pubmed/31557367
http://dx.doi.org/10.1002/anie.201909126