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A Long‐Lived Azafullerenyl Radical Stabilized by Supramolecular Shielding with a [10]Cycloparaphenylene
A major handicap towards the exploitation of radicals is their inherent instability. In the paramagnetic azafullerenyl radical C(59)N(.), the unpaired electron is strongly localized next to the nitrogen atom, which induces dimerization to diamagnetic bis(azafullerene), (C(59)N)(2). Conventional stab...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7003913/ https://www.ncbi.nlm.nih.gov/pubmed/31557367 http://dx.doi.org/10.1002/anie.201909126 |