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Chiroptical inversion of a planar chiral redox-switchable rotaxane
A tetrathiafulvalene (TTF)-containing crown ether macrocycle with C(s) symmetry was designed to implement planar chirality into a redox-active [2]rotaxane. The directionality of the macrocycle atom sequence together with the non-symmetric axle renders the corresponding [2]rotaxane mechanically plana...
Autores principales: | , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7003955/ https://www.ncbi.nlm.nih.gov/pubmed/32055357 http://dx.doi.org/10.1039/c9sc03694f |