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A macrocyclic oligofuran: synthesis, solid state structure and electronic properties

We report the first π-conjugated macrocyclic system with an oligofuran backbone. The calculated HOMO–LUMO gap is similar to that of the corresponding linear polymer, indicating a remarkable electron delocalization. The X-ray structure reveals a planar conformation, in contrast to the twisted conform...

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Detalles Bibliográficos
Autores principales: Mulay, Sandip V., Dishi, Or, Fang, Yuan, Niazi, Muhammad R., Shimon, Linda J. W., Perepichka, Dmitrii F., Gidron, Ori
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7003964/
https://www.ncbi.nlm.nih.gov/pubmed/32055302
http://dx.doi.org/10.1039/c9sc03247a