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Tertiary amine-directed and involved carbonylative cyclizations through Pd/Cu-cocatalyzed multiple C–X (X = H or N) bond cleavage

A novel Pd/Cu-cocatalyzed carbonylative cyclization by C–H activation and N-dealkylative C–N bond activation has been developed for the chemoselective construction of synthetically useful heterocycles. The N,N-dimethylamine group on o-indolyl-N,N-dimethylarylamines was found to act as both the direc...

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Detalles Bibliográficos
Autores principales: Mu, Qiu-Chao, Nie, Yi-Xue, Bai, Xing-Feng, Chen, Jing, Yang, Lei, Xu, Zheng, Li, Li, Xia, Chun-Gu, Xu, Li-Wen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7003976/
https://www.ncbi.nlm.nih.gov/pubmed/32055315
http://dx.doi.org/10.1039/c9sc03081f