Electrochemically Tunable Proton‐Coupled Electron Transfer in Pd‐Catalyzed Benzaldehyde Hydrogenation

Acid functionalization of a carbon support allows to enhance the electrocatalytic activity of Pd to hydrogenate benzaldehyde to benzyl alcohol proportional to the concentration of Brønsted‐acid sites. In contrast, the hydrogenation rate is not affected when H(2) is used as a reduction equivalent. Th...

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Detalles Bibliográficos
Autores principales: Koh, Katherine, Sanyal, Udishnu, Lee, Mal‐Soon, Cheng, Guanhua, Song, Miao, Glezakou, Vassiliki‐Alexandra, Liu, Yue, Li, Dongsheng, Rousseau, Roger, Gutiérrez, Oliver Y., Karkamkar, Abhijeet, Derewinski, Miroslaw, Lercher, Johannes A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7004174/
https://www.ncbi.nlm.nih.gov/pubmed/31634416
http://dx.doi.org/10.1002/anie.201912241

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7004174/
https://www.ncbi.nlm.nih.gov/pubmed/31634416
http://dx.doi.org/10.1002/anie.201912241

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