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Proline-promoted dehydroxylation of α-ketols

A new single-step proline-potassium acetate promoted reductive dehydroxylation of α-ketols is reported. We introduce the unexplored reactivity of proline and, for the first time, reveal its ability to function as a reducing agent. The developed metal-free and open-flask operation generally results i...

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Detalles Bibliográficos
Autores principales: Mostinski, Yelena, Lankri, David, Konovalov, Yana, Nataf, Riva, Tsvelikhovsky, Dmitry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7006627/
https://www.ncbi.nlm.nih.gov/pubmed/32110298
http://dx.doi.org/10.1039/c9sc02543j