Cargando…

Divergent Catalytic Strategies for the Cis/Trans Stereoselective Ring-Opening Polymerization of a Dual Cyclic Carbonate/Olefin Monomer

[Image: see text] A dual seven-membered cyclic carbonate/olefin monomer was synthesized from CO(2) and cis-1,4-butenediol and polymerized. The properties of the polymer were controlled using divergent catalytic strategies toward the stereochemistry of the olefin. Ring-opening polymerization of the c...

Descripción completa

Detalles Bibliográficos
Autores principales: McGuire, Thomas M., Pérale, Cécile, Castaing, Rémi, Kociok-Köhn, Gabriele, Buchard, Antoine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7007229/
https://www.ncbi.nlm.nih.gov/pubmed/31429566
http://dx.doi.org/10.1021/jacs.9b06259