Highly Enantioselective Hiyama Cross-Coupling via Rh-Catalyzed Allylic Arylation of Racemic Allyl Chlorides

[Image: see text] Highly enantioselective Hiyama cross-coupling reactions have been achieved through rhodium(I)-catalyzed dynamic kinetic asymmetric transformations between aryl siloxanes and cyclic racemic allyl halides. This process affords valuable enantiomerically enriched aryl-substituted cycli...

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Detalles Bibliográficos
Autores principales: González, Jesús, Schäfer, Philipp, Fletcher, Stephen P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7009026/
https://www.ncbi.nlm.nih.gov/pubmed/32055086
http://dx.doi.org/10.1021/acs.organomet.9b00197

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7009026/
https://www.ncbi.nlm.nih.gov/pubmed/32055086
http://dx.doi.org/10.1021/acs.organomet.9b00197

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