Iron-Catalyzed Borrowing Hydrogen β-C(sp(3))-Methylation of Alcohols

[Image: see text] Herein we report the iron-catalyzed β-C(sp(3))-methylation of primary alcohols using methanol as a C1 building block. This borrowing hydrogen approach employs a well-defined bench-stable (cyclopentadienone)iron(0) carbonyl complex as precatalyst (5 mol %) and enables a diverse sele...

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Detalles Bibliográficos
Autores principales: Polidano, Kurt, Williams, Jonathan M. J., Morrill, Louis C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7011770/
https://www.ncbi.nlm.nih.gov/pubmed/32064149
http://dx.doi.org/10.1021/acscatal.9b02461

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7011770/
https://www.ncbi.nlm.nih.gov/pubmed/32064149
http://dx.doi.org/10.1021/acscatal.9b02461

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