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Iron-Catalyzed Borrowing Hydrogen β-C(sp(3))-Methylation of Alcohols
[Image: see text] Herein we report the iron-catalyzed β-C(sp(3))-methylation of primary alcohols using methanol as a C1 building block. This borrowing hydrogen approach employs a well-defined bench-stable (cyclopentadienone)iron(0) carbonyl complex as precatalyst (5 mol %) and enables a diverse sele...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7011770/ https://www.ncbi.nlm.nih.gov/pubmed/32064149 http://dx.doi.org/10.1021/acscatal.9b02461 |