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Transition Metal Coordination Polymers with Trans-1,4-Cyclohexanedicarboxylate: Acidity-Controlled Synthesis, Structures and Properties

Five trans-1,4-cyclohexanedicarboxylate (chdc(2−)) metal–organic frameworks of transition metals were synthesized in aqueous systems. A careful control of pH, reaction temperature and solvent composition were shown to direct the crystallization of a particular compound. Isostructural [Co(H(2)O)(4)(c...

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Detalles Bibliográficos
Autores principales: Demakov, Pavel A., Bogomyakov, Artem S., Urlukov, Artem S., Andreeva, Aleksandra Yu., Samsonenko, Denis G., Dybtsev, Danil N., Fedin, Vladimir P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7014088/
https://www.ncbi.nlm.nih.gov/pubmed/31963949
http://dx.doi.org/10.3390/ma13020486