Electrochemical C–H bond activation via cationic iridium hydride pincer complexes

A C–H bond activation strategy based on electrochemical activation of a metal hydride is introduced. Electrochemical oxidation of ((tBu(4))PCP)IrH(4) ((tBu(4))PCP is [1,3-((t)Bu(2)PCH(2))-C(6)H(3)](–)) in the presence of pyridine derivatives generates cationic Ir hydride complexes of the type [((tBu...

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Detalles Bibliográficos
Autores principales: Lindley, Brian M., Walden, Andrew G., Brasacchio, Ann Marie, Casuras, Andrea, Lease, Nicholas, Chen, Chun-Hsing, Goldman, Alan S., Miller, Alexander J. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7017868/
https://www.ncbi.nlm.nih.gov/pubmed/32110295
http://dx.doi.org/10.1039/c9sc03076j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7017868/
https://www.ncbi.nlm.nih.gov/pubmed/32110295
http://dx.doi.org/10.1039/c9sc03076j

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