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Electrochemical C–H bond activation via cationic iridium hydride pincer complexes
A C–H bond activation strategy based on electrochemical activation of a metal hydride is introduced. Electrochemical oxidation of ((tBu(4))PCP)IrH(4) ((tBu(4))PCP is [1,3-((t)Bu(2)PCH(2))-C(6)H(3)](–)) in the presence of pyridine derivatives generates cationic Ir hydride complexes of the type [((tBu...
Autores principales: | Lindley, Brian M., Walden, Andrew G., Brasacchio, Ann Marie, Casuras, Andrea, Lease, Nicholas, Chen, Chun-Hsing, Goldman, Alan S., Miller, Alexander J. M. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7017868/ https://www.ncbi.nlm.nih.gov/pubmed/32110295 http://dx.doi.org/10.1039/c9sc03076j |
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