Highly selective hydrogenation of amides catalysed by a molybdenum pincer complex: scope and mechanism

A series of molybdenum pincer complexes has been shown for the first time to be active in the catalytic hydrogenation of amides. Among the tested catalysts, Mo-1a proved to be particularly well suited for the selective C–N hydrogenolysis of N-methylated formanilides. Notably, high chemoselectivity w...

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Detalles Bibliográficos
Autores principales: Leischner, Thomas, Artús Suarez, Lluis, Spannenberg, Anke, Junge, Kathrin, Nova, Ainara, Beller, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7020655/
https://www.ncbi.nlm.nih.gov/pubmed/32110342
http://dx.doi.org/10.1039/c9sc03453f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7020655/
https://www.ncbi.nlm.nih.gov/pubmed/32110342
http://dx.doi.org/10.1039/c9sc03453f

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