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Cu-catalyzed C–C bond formation of vinylidene cyclopropanes with carbon nucleophiles

The development of Cu-catalyzed addition of carbon nucleophiles to vinylidene cyclopropanes was reported. The reactions with 1,1-bisborylmethane provided homopropargylic boronate products by forming a C–C bond at the terminal carbon atom of the allene moiety of vinylidene cyclopropanes. Alkynyl boro...

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Detalles Bibliográficos
Autores principales: Chen, Jichao, Gao, Shang, Chen, Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7020789/
https://www.ncbi.nlm.nih.gov/pubmed/32110346
http://dx.doi.org/10.1039/c9sc04122b