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Base-Promoted C–C Bond Activation Enables Radical Allylation with Homoallylic Alcohols
[Image: see text] The C(α)–C(β) bond in homoallylic alcohols can be activated under basic conditions, qualifying these nonstrained acyclic systems as radical allylation reagents. This reactivity is exemplified by photoinitiated (with visible light and/or blue LEDs) allylation of perfluoroalkyl and a...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7021447/ https://www.ncbi.nlm.nih.gov/pubmed/31941267 http://dx.doi.org/10.1021/jacs.9b12343 |