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N‐Heterocyclic Carbene Catalyzed Photoenolization/Diels–Alder Reaction of Acid Fluorides

The combination of light activation and N‐heterocyclic carbene (NHC) organocatalysis has enabled the use of acid fluorides as substrates in a UVA‐light‐mediated photochemical transformation previously observed only with aromatic aldehydes and ketones. Stoichiometric studies and TD‐DFT calculations s...

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Detalles Bibliográficos
Autores principales: Mavroskoufis, Andreas, Rajes, Keerthana, Golz, Paul, Agrawal, Arush, Ruß, Vincent, Götze, Jan P., Hopkinson, Matthew N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7027522/
https://www.ncbi.nlm.nih.gov/pubmed/31814280
http://dx.doi.org/10.1002/anie.201914456