Cargando…
N‐Heterocyclic Carbene Catalyzed Photoenolization/Diels–Alder Reaction of Acid Fluorides
The combination of light activation and N‐heterocyclic carbene (NHC) organocatalysis has enabled the use of acid fluorides as substrates in a UVA‐light‐mediated photochemical transformation previously observed only with aromatic aldehydes and ketones. Stoichiometric studies and TD‐DFT calculations s...
Autores principales: | Mavroskoufis, Andreas, Rajes, Keerthana, Golz, Paul, Agrawal, Arush, Ruß, Vincent, Götze, Jan P., Hopkinson, Matthew N. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7027522/ https://www.ncbi.nlm.nih.gov/pubmed/31814280 http://dx.doi.org/10.1002/anie.201914456 |
Ejemplares similares
-
A (TD-)DFT study on photo-NHC catalysis: photoenolization/Diels–Alder reaction of acid fluorides catalyzed by N-heterocyclic carbenes
por: Mavroskoufis, Andreas, et al.
Publicado: (2023) -
Construction of polycyclic structures with vicinal all-carbon quaternary stereocenters via an enantioselective photoenolization/Diels–Alder reaction
por: Hou, Min, et al.
Publicado: (2021) -
Ti(Oi-Pr)(4)-promoted photoenolization Diels–Alder reaction to construct polycyclic rings and its synthetic applications
por: Yang, Baochao, et al.
Publicado: (2017) -
How Ionization Catalyzes Diels‐Alder Reactions
por: Vermeeren, Pascal, et al.
Publicado: (2022) -
How Bases Catalyze Diels‐Alder Reactions
por: Yu, Song, et al.
Publicado: (2022)