Remote Perfluoroalkyl Substituents are Key to Living Aqueous Ethylene Polymerization

In various nickel(II) salicylaldiminato ethylene polymerization catalysts, which are a versatile mechanistic probe for substituent effects, longer perfluoroalkyl groups exert a strong effect on catalytic activities and polymer microstructures compared to the trifluoromethyl group. This effect is acc...

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Detalles Bibliográficos
Autores principales: Schnitte, Manuel, Scholliers, Janine S., Riedmiller, Kai, Mecking, Stefan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7027523/
https://www.ncbi.nlm.nih.gov/pubmed/31773825
http://dx.doi.org/10.1002/anie.201913117

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7027523/
https://www.ncbi.nlm.nih.gov/pubmed/31773825
http://dx.doi.org/10.1002/anie.201913117

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