Cargando…

Remote Perfluoroalkyl Substituents are Key to Living Aqueous Ethylene Polymerization

In various nickel(II) salicylaldiminato ethylene polymerization catalysts, which are a versatile mechanistic probe for substituent effects, longer perfluoroalkyl groups exert a strong effect on catalytic activities and polymer microstructures compared to the trifluoromethyl group. This effect is acc...

Descripción completa

Detalles Bibliográficos
Autores principales:	Schnitte, Manuel, Scholliers, Janine S., Riedmiller, Kai, Mecking, Stefan
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7027523/ https://www.ncbi.nlm.nih.gov/pubmed/31773825 http://dx.doi.org/10.1002/anie.201913117

Ejemplares similares

Uniform shape monodisperse single chain nanocrystals by living aqueous catalytic polymerization
por: Schnitte, Manuel, et al.
Publicado: (2019)

Hydrophilic Catalysts with High Activity and Stability in the Aqueous Polymerization of Ethylene to High‐Molecular‐Weight‐Polyethylene
por: Lin, Fei, et al.
Publicado: (2022)

Fluorinated Sterically Bulky Mononuclear and Binuclear 2-Iminopyridylnickel Halides for Ethylene Polymerization: Effects of Ligand Frameworks and Remote Substituents
por: Zhang, Qiuyue, et al.
Publicado: (2021)

Ortho-Functionalized Dibenzhydryl Substituents in α-Diimine Pd Catalyzed Ethylene Polymerization and Copolymerization
por: Muhammad, Qasim, et al.
Publicado: (2020)

Enhancing Ethylene Polymerization of NNN-Cobalt(II) Precatalysts Adorned with a Fluoro-substituent
por: Bariashir, Chantsalnyam, et al.
Publicado: (2021)

4,4′-Dimethoxybenzhydryl substituent augments performance of bis(imino)pyridine cobalt-based catalysts in ethylene polymerization
por: Yuan, Shi-Fang, et al.
Publicado: (2022)

Encapsulation of catalyst in block copolymer micelles for the polymerization of ethylene in aqueous medium
por: Boucher-Jacobs, Camille, et al.
Publicado: (2018)

Molecular interactions in short-chain perfluoroalkyl carboxylic acids and aqueous solutions
por: Benmore, Chris J., et al.
Publicado: (2023)

Enantioselective catalytic remote perfluoroalkylation of α-branched enals driven by light
por: Balletti, Matteo, et al.
Publicado: (2023)

Coordinative Chain Transfer Polymerization of Butadiene with Functionalized Aluminum Reagents
por: Göttker‐Schnetmann, Inigo, et al.
Publicado: (2019)

Mechanistic Insights into Ni(II)-Catalyzed Nonalternating Ethylene–Carbon Monoxide Copolymerization
por: Voccia, Maria, et al.
Publicado: (2022)

The Highly Controlled and Efficient Polymerization of Ethylene
por: Goller, Alexander, et al.
Publicado: (2023)

“Living” Polymerization of Ethylene and 1-Hexene Using Novel Binuclear Pd–Diimine Catalysts
por: Ye, Jianding, et al.
Publicado: (2017)

Neutral Unsymmetrical Coordinated Cyclophane Polymerization Catalysts
por: Schiebel, Eva, et al.
Publicado: (2021)

Tuning the Binding Strength of Even and Uneven Hydrogen-Bonded Arrays with Remote Substituents
por: van der Lubbe, Stephanie C. C., et al.
Publicado: (2020)

One-Step Aqueous Spraying Process for the Fabrication of Omniphobic Fabrics Free of Long Perfluoroalkyl Chains
por: Cai, Ronggang, et al.
Publicado: (2019)

Selective branch formation in ethylene polymerization to access precise ethylene-propylene copolymers
por: Zhang, Yuxing, et al.
Publicado: (2022)

Influences of Fluorine Substituents on Iminopyridine Fe(II)- and Co(II)-Catalyzed Isoprene Polymerization
por: Zhu, Guangqian, et al.
Publicado: (2018)

Octahedral Zirconium Salan Catalysts for Olefin Polymerization: Substituent and Solvent Effects on Structure and Dynamics
por: Dall’Anese, Anna, et al.
Publicado: (2023)

Dehydration of (Perfluoroalkyl)tetramethylcyclopentenol
por: Čermák, Jan, et al.
Publicado: (2011)

Gas phase polymerization of ethylene towards UHMWPE
por: GEÇİM, Gözde, et al.
Publicado: (2020)

Substituent Effects on the Photodeprotection Reactions of Selected Ketoprofen Derivatives in Phosphate Buffered Aqueous Solutions
por: Liu, Mingyue, et al.
Publicado: (2016)

Synthesis of 2-Substitued Indoles via Pd-Catalysed Cyclization in an Aqueous Micellar Medium
por: Siciliano, Sofia, et al.
Publicado: (2021)

Nitrifying Microorganisms Linked to Biotransformation of Perfluoroalkyl Sulfonamido Precursors from Legacy Aqueous Film-Forming Foams
por: Ruyle, Bridger J., et al.
Publicado: (2023)

Influences of Alkyl and Aryl Substituents on Iminopyridine Fe(II)- and Co(II)-Catalyzed Isoprene Polymerization
por: Guo, Lihua, et al.
Publicado: (2016)

The Stronger the Better: Donor Substituents Push Catalytic Activity of Molecular Chromium Olefin Polymerization Catalysts
por: Hansen, Helge‐Boj, et al.
Publicado: (2021)

Thyroid Function and Perfluoroalkyl Acids in Children Living Near a Chemical Plant
por: Lopez-Espinosa, Maria-Jose, et al.
Publicado: (2012)

High Temperature, Living Polymerization of Ethylene by a Sterically-Demanding Nickel(II) α-Diimine Catalyst
por: Brown, Lauren A., et al.
Publicado: (2018)

Constructing New Expertise: Private and Public Initiatives for Safe Food (Brussels in the First Half of the Nineteenth Century)
por: Scholliers, Peter
Publicado: (2014)

Synthesis and ethylene polymerization reaction of dendritic titanium catalysts
por: Lan, Tianyu, et al.
Publicado: (2021)

RAFT Aqueous Dispersion Polymerization Yields Poly(ethylene glycol)-Based Diblock Copolymer Nano-Objects with Predictable Single Phase Morphologies
por: Warren, Nicholas J., et al.
Publicado: (2013)

Interplay of Protecting Groups and Side Chain Conformation in Glycopyranosides. Modulation of the Influence of Remote Substituents on Glycosylation?
por: Dharuman, Suresh, et al.
Publicado: (2018)

Key scientific issues in developing drinking water guidelines for perfluoroalkyl acids: Contaminants of emerging concern
por: Post, Gloria B., et al.
Publicado: (2017)

Poly(ethylene oxide) Is Positively Charged in Aqueous Solutions
por: Zhou, Chao, et al.
Publicado: (2022)

Occurrence, temporal trends, and half-lives of perfluoroalkyl acids (PFAAs) in occupational workers in China
por: Fu, Jianjie, et al.
Publicado: (2016)

Zeta Potential of Nanosilica in 50% Aqueous Ethylene Glycol and in 50% Aqueous Propylene Glycol
por: Kosmulski, Marek, et al.
Publicado: (2023)

Substituent Pattern Effects on the Redox Potentials of Quinone‐Based Active Materials for Aqueous Redox Flow Batteries
por: Schwan, S., et al.
Publicado: (2020)

Perfluoroalkylation of Aryl-N,N-dimethyl Hydrazones Using Hypervalent Iodine(III) Reagents or Perfluoroalkyl Iodides
por: Janhsen, Benjamin, et al.
Publicado: (2017)

6-Arylimino-2-(2-(1-phenylethyl)naphthalen-1-yl)-iminopyridylmetal (Fe and Co) Complexes as Highly Active Precatalysts for Ethylene Polymerization: Influence of Metal and/or Substituents on the Active, Thermostable Performance of Their Complexes and Resultant Polyethylenes
por: Lin, Wenhua, et al.
Publicado: (2020)

Active Sites in a Heterogeneous Organometallic Catalyst for the Polymerization of Ethylene
por: Culver, Damien B., et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_hhqog7qouvruraoq9snsl3bkfs