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Structure–Solubility Relationship of 1,4‐Dioxane Complexes of Di(hydrocarbyl)magnesium

Systematic variation of the 1,4‐dioxane (dx) concentration during the precipitation of sparingly soluble [MgBr(2)(dx)(2)] from ethereal Grignard solutions of RMgBr has allowed the structural investigation of crystallized [R(2)Mg(dx)(n)] (n=1, 1.5, 2, and 3), which form during this dioxane method, de...

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Detalles Bibliográficos
Autores principales: Fischer, Reinald, Görls, Helmar, Meisinger, Philippe R., Suxdorf, Regina, Westerhausen, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7027550/
https://www.ncbi.nlm.nih.gov/pubmed/31328293
http://dx.doi.org/10.1002/chem.201903120