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Tuning Pt(II)‐Based Donor–Acceptor Systems through Ligand Design: Effects on Frontier Orbitals, Redox Potentials, UV/Vis/NIR Absorptions, Electrochromism, and Photocatalysis

Asymmetric platinum donor–acceptor complexes [(pimp)Pt(Q(2−))] are presented in this work, in which pimp=[(2,4,6‐trimethylphenylimino)methyl]pyridine and Q(2−)=catecholate‐type donor ligands. The properties of the complexes are evaluated as a function of the donor ligands, and correlations are drawn...

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Detalles Bibliográficos
Autores principales: Sobottka, Sebastian, Nößler, Maite, Ostericher, Andrew L., Hermann, Gunter, Subat, Noah Z., Beerhues, Julia, Behr‐van der Meer, Margarethe, Suntrup, Lisa, Albold, Uta, Hohloch, Stephan, Tremblay, Jean Christophe, Sarkar, Biprajit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7027812/
https://www.ncbi.nlm.nih.gov/pubmed/31778594
http://dx.doi.org/10.1002/chem.201903700