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Tuning Pt(II)‐Based Donor–Acceptor Systems through Ligand Design: Effects on Frontier Orbitals, Redox Potentials, UV/Vis/NIR Absorptions, Electrochromism, and Photocatalysis
Asymmetric platinum donor–acceptor complexes [(pimp)Pt(Q(2−))] are presented in this work, in which pimp=[(2,4,6‐trimethylphenylimino)methyl]pyridine and Q(2−)=catecholate‐type donor ligands. The properties of the complexes are evaluated as a function of the donor ligands, and correlations are drawn...
Autores principales: | , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7027812/ https://www.ncbi.nlm.nih.gov/pubmed/31778594 http://dx.doi.org/10.1002/chem.201903700 |