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(Me)CAAC=N(−): A Cyclic (Alkyl)(Amino)Carbene Imino Ligand
A cyclic (alkyl)(amino)carbene (CAAC) has been shown to react with a covalent azide similar to the Staudinger reaction. The reaction of (Me)CAAC with trimethylsilyl azide afforded the N‐silylated 2‐iminopyrrolidine ((Me)CAAC=NSiMe(3)), which was fully characterized. This compound undergoes hydrolysi...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7027825/ https://www.ncbi.nlm.nih.gov/pubmed/31777982 http://dx.doi.org/10.1002/chem.201904715 |