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(Me)CAAC=N(−): A Cyclic (Alkyl)(Amino)Carbene Imino Ligand

A cyclic (alkyl)(amino)carbene (CAAC) has been shown to react with a covalent azide similar to the Staudinger reaction. The reaction of (Me)CAAC with trimethylsilyl azide afforded the N‐silylated 2‐iminopyrrolidine ((Me)CAAC=NSiMe(3)), which was fully characterized. This compound undergoes hydrolysi...

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Detalles Bibliográficos
Autores principales:	Goettel, James T., Gao, Haopeng, Dotzauer, Simon, Braunschweig, Holger
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7027825/ https://www.ncbi.nlm.nih.gov/pubmed/31777982 http://dx.doi.org/10.1002/chem.201904715

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