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Exopolyhedral Ligand Orientation Controls Diastereoisomer in Mixed-Metal Bis(Carboranes) †

Heterobimetallic derivatives of a bis(carborane), [μ(7,8)-(1′,3′−3′-Cl-3′-PPh(3)-closo-3′,1′,2′-RhC(2)B(9)H(10))-2-(p-cymene)-closo-2,1,8-RuC(2)B(9)H(10)] (1) and [μ(7,8)-(1′,3′−3′-Cl-3′-PPh(3)-closo-3′,1′,2′-RhC(2)B(9)H(10))-2-Cp-closo-2,1,8-CoC(2)B(9)H(10)] (2) have been synthesised and characteri...

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Detalles Bibliográficos
Autores principales: Chan, Antony P. Y., Rosair, Georgina M., Welch, Alan J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7037510/
https://www.ncbi.nlm.nih.gov/pubmed/31991685
http://dx.doi.org/10.3390/molecules25030519