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Exopolyhedral Ligand Orientation Controls Diastereoisomer in Mixed-Metal Bis(Carboranes) †
Heterobimetallic derivatives of a bis(carborane), [μ(7,8)-(1′,3′−3′-Cl-3′-PPh(3)-closo-3′,1′,2′-RhC(2)B(9)H(10))-2-(p-cymene)-closo-2,1,8-RuC(2)B(9)H(10)] (1) and [μ(7,8)-(1′,3′−3′-Cl-3′-PPh(3)-closo-3′,1′,2′-RhC(2)B(9)H(10))-2-Cp-closo-2,1,8-CoC(2)B(9)H(10)] (2) have been synthesised and characteri...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7037510/ https://www.ncbi.nlm.nih.gov/pubmed/31991685 http://dx.doi.org/10.3390/molecules25030519 |