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Exploration of Mechanochemical Activation in Solid-State Fluoro-Grignard Reactions
Owing to the strength of the C–F bond, the ‘direct’ preparation of Grignard reagents, i.e., the interaction of elemental magnesium with an organic halide, typically in an ethereal solvent, fails for bulk magnesium and organofluorine compounds. Previously described mechanochemical methods for prepari...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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MDPI
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7037680/ https://www.ncbi.nlm.nih.gov/pubmed/32012963 http://dx.doi.org/10.3390/molecules25030570 |