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Exploring the Scope of Macrocyclic “Shoe-last” Templates in the Mechanochemical Synthesis of RHO Topology Zeolitic Imidazolate Frameworks (ZIFs)

The macrocyclic cavitand MeMeCH(2) is used as a template for the mechanochemical synthesis of 0.2MeMeCH(2)@RHO-Zn(16)(Cl(2)Im)(32) (0.2MeMeCH(2)@ZIF-71) and RHO-ZnBIm(2) (ZIF-11) zeolitic imidazolate frameworks (ZIFs). It is shown that MeMeCH(2) significantly accelerates the mechanochemical synthesi...

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Detalles Bibliográficos
Autores principales: Brekalo, Ivana, Deliz, David E., Kane, Christopher M., Friščić, Tomislav, Holman, K. Travis
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7037713/
https://www.ncbi.nlm.nih.gov/pubmed/32024141
http://dx.doi.org/10.3390/molecules25030633