Cargando…
Phenolic Hydrogen Transfer by Molecular Oxygen and Hydroperoxyl Radicals. Insights into the Mechanism of the Anthraquinone Process
[Image: see text] Hydrogen atom transfer (HAT) by (3)O(2) and HO(2)(•) from arenols (ArOH), aryloxyls (ArO(•)), their tautomers (ArH), and auxiliary compounds has been investigated by means of CBS-QB3 computations. With (3)O(2), excellent linear correlations have been found between the activation en...
| Autores principales: | , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2020
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7040920/ https://www.ncbi.nlm.nih.gov/pubmed/31922747 http://dx.doi.org/10.1021/acs.joc.9b03286 |