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Elucidating the mechanism of heterogeneous Wacker oxidation over Pd-Cu/zeolite Y by transient XAS

The heterogenization of Wacker catalysts using chloride-free systems can potentially be a good alternative for the commercial homogeneous Wacker oxidation of ethylene, which utilizes excessive aqueous chloride solvents. However, the mechanism of the heterogeneous system has not been clarified, preve...

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Detalles Bibliográficos
Autores principales: Imbao, Jerick, van Bokhoven, Jeroen A., Clark, Adam, Nachtegaal, Maarten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7048791/
https://www.ncbi.nlm.nih.gov/pubmed/32111846
http://dx.doi.org/10.1038/s41467-020-14982-x