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Infrared Multiple Photon Dissociation Spectroscopy of Hydrated Cobalt Anions Doped with Carbon Dioxide CoCO(2)(H(2)O)(n) (−), n=1–10, in the C−O Stretch Region

We investigate anionic [Co,CO(2),nH(2)O](−) clusters as model systems for the electrochemical activation of CO(2) by infrared multiple photon dissociation (IRMPD) spectroscopy in the range of 1250–2234 cm(−1) using an FT‐ICR mass spectrometer. We show that both CO(2) and H(2)O are activated in a sig...

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Detalles Bibliográficos
Autores principales: Barwa, Erik, Ončák, Milan, Pascher, Tobias F., Herburger, Andreas, van der Linde, Christian, Beyer, Martin K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7051846/
https://www.ncbi.nlm.nih.gov/pubmed/31617628
http://dx.doi.org/10.1002/chem.201904182