Cargando…
Infrared Multiple Photon Dissociation Spectroscopy of Hydrated Cobalt Anions Doped with Carbon Dioxide CoCO(2)(H(2)O)(n) (−), n=1–10, in the C−O Stretch Region
We investigate anionic [Co,CO(2),nH(2)O](−) clusters as model systems for the electrochemical activation of CO(2) by infrared multiple photon dissociation (IRMPD) spectroscopy in the range of 1250–2234 cm(−1) using an FT‐ICR mass spectrometer. We show that both CO(2) and H(2)O are activated in a sig...
Autores principales: | Barwa, Erik, Ončák, Milan, Pascher, Tobias F., Herburger, Andreas, van der Linde, Christian, Beyer, Martin K. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7051846/ https://www.ncbi.nlm.nih.gov/pubmed/31617628 http://dx.doi.org/10.1002/chem.201904182 |
Ejemplares similares
-
Probing
the Structural Evolution of the Hydrated Electron
in Water Cluster Anions (H(2)O)(n)(–), n ≤ 200, by Electronic
Absorption Spectroscopy
por: Herburger, Andreas, et al.
Publicado: (2019) -
Infrared Spectroscopy of Size‐Selected Hydrated Carbon Dioxide Radical Anions CO(2)
(.−)(H(2)O)(n) (n=2–61) in the C−O Stretch Region
por: Herburger, Andreas, et al.
Publicado: (2019) -
Carbon Dioxide Activation at Metal Centers: Evolution of Charge Transfer from Mg (.+) to CO(2) in [MgCO(2)(H(2)O)(n)](.+), n=0–8
por: Barwa, Erik, et al.
Publicado: (2020) -
CO(2)/O(2) Exchange in Magnesium–Water
Clusters Mg(+)(H(2)O)(n)
por: Barwa, Erik, et al.
Publicado: (2018) -
Electronic spectroscopy and nanocalorimetry of hydrated magnesium ions [Mg(H(2)O)(n)](+), n = 20–70: spontaneous formation of a hydrated electron?
por: Taxer, Thomas, et al.
Publicado: (2019)