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Incorporation of Cr(III) into a Keggin Polyoxometalate as a Chemical Strategy to Stabilize a Labile {Cr(III)O(4)} Tetrahedral Conformation and Promote Unattended Single-Ion Magnet Properties
[Image: see text] Polyoxometalates (POMs) provide rigid and highly symmetric coordination sites and can be used as a strategy for the stabilization of magnetic ions. Herein, we report a new member of the Keggin archetype, the Cr-centered Keggin anion [α-CrW(12)O(40)](5–) (CrW(12)), with the unusual...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7052816/ https://www.ncbi.nlm.nih.gov/pubmed/31967803 http://dx.doi.org/10.1021/jacs.9b12797 |