A dual photoredox-nickel strategy for remote functionalization via iminyl radicals: radical ring-opening-arylation, -vinylation and -alkylation cascades

A divergent strategy for the remote arylation, vinylation and alkylation of nitriles is described. These processes proceed through the photoredox generation of a cyclic iminyl radical and its following ring-opening reaction. The distal nitrile radical is then engaged in nickel-based catalytic cycles...

Descripción completa

Detalles Bibliográficos
Autores principales: Dauncey, Elizabeth M., Dighe, Shashikant U., Douglas, James J., Leonori, Daniele
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7053659/
https://www.ncbi.nlm.nih.gov/pubmed/32180920
http://dx.doi.org/10.1039/c9sc02616a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7053659/
https://www.ncbi.nlm.nih.gov/pubmed/32180920
http://dx.doi.org/10.1039/c9sc02616a

Ejemplares similares