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Synthesis and crystal structure of (1,4,7,10-tetra­aza­cyclo­dodecane-κ(4) N)(tetra­sulfido-κ(2) S (1),S (4))manganese(II)

The title compound, [Mn(S(4))(C(8)H(20)N(4))], was accidentally obtained by the hydro­thermal reaction of Mn(ClO(4))(2)·6H(2)O, cyclen (cyclen = 1,4,7,10-tetra­aza­cyclo­dodeca­ne) and Na(3)SbS(4)·9H(2)O in water at 413 K, indicating that polysulfide anions might represent inter­mediates in the synt...

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Detalles Bibliográficos
Autores principales: Danker, Felix, Näther, Christian, Bensch, Wolfgang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7057377/
https://www.ncbi.nlm.nih.gov/pubmed/32148894
http://dx.doi.org/10.1107/S2056989020002492