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Rational selection of co-catalysts for the deaminative hydrogenation of amides

The catalytic hydrogenation of amides is an atom economical method to synthesize amines. Previously, it was serendipitously discovered that the combination of a secondary amide co-catalyst with ((iPr)PNP)Fe(H)(CO) ((iPr)PNP = N[CH(2)CH(2)(P(i)Pr(2))](2)(–)), results in a highly active base metal sys...

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Detalles Bibliográficos
Autores principales: Artús Suàrez, Lluís, Jayarathne, Upul, Balcells, David, Bernskoetter, Wesley H., Hazari, Nilay, Jaraiz, Martín, Nova, Ainara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7059200/
https://www.ncbi.nlm.nih.gov/pubmed/32190278
http://dx.doi.org/10.1039/c9sc03812d