Eu(O(2)C‐C≡C‐CO(2)): An Eu(II) Containing Anhydrous Coordination Polymer with High Stability and Negative Thermal Expansion

Anhydrous Eu(II)–acetylenedicarboxylate (EuADC; ADC(2−) = (−)O(2)C‐C≡C‐CO(2) (−)) was synthesized by reaction of EuBr(2) with K(2)ADC or H(2)ADC in degassed water under oxygen‐free conditions. EuADC crystallizes in the SrADC type structure (I4(1)/amd, Z=4) forming a 3D coordination polymer with a di...

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Detalles Bibliográficos
Autores principales: Gramm, Verena K., Smets, Daniel, Grzesiak, Ireneus, Block, Theresa, Pöttgen, Rainer, Suta, Markus, Wickleder, Claudia, Lorenz, Thomas, Ruschewitz, Uwe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7065108/
https://www.ncbi.nlm.nih.gov/pubmed/31774598
http://dx.doi.org/10.1002/chem.201904966

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7065108/
https://www.ncbi.nlm.nih.gov/pubmed/31774598
http://dx.doi.org/10.1002/chem.201904966

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