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Single‐Molecule Magnets DyM(2)N@C(80) and Dy(2)MN@C(80) (M=Sc, Lu): The Impact of Diamagnetic Metals on Dy(3+) Magnetic Anisotropy, Dy⋅⋅⋅Dy Coupling, and Mixing of Molecular and Lattice Vibrations
The substitution of scandium in fullerene single‐molecule magnets (SMMs) DySc(2)N@C(80) and Dy(2)ScN@C(80) by lutetium has been studied to explore the influence of the diamagnetic metal on the SMM performance of dysprosium nitride clusterfullerenes. The use of lutetium led to an improved SMM perform...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7065109/ https://www.ncbi.nlm.nih.gov/pubmed/31774196 http://dx.doi.org/10.1002/chem.201904879 |