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Single‐Molecule Magnets DyM(2)N@C(80) and Dy(2)MN@C(80) (M=Sc, Lu): The Impact of Diamagnetic Metals on Dy(3+) Magnetic Anisotropy, Dy⋅⋅⋅Dy Coupling, and Mixing of Molecular and Lattice Vibrations

The substitution of scandium in fullerene single‐molecule magnets (SMMs) DySc(2)N@C(80) and Dy(2)ScN@C(80) by lutetium has been studied to explore the influence of the diamagnetic metal on the SMM performance of dysprosium nitride clusterfullerenes. The use of lutetium led to an improved SMM perform...

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Detalles Bibliográficos
Autores principales:	Spree, Lukas, Schlesier, Christin, Kostanyan, Aram, Westerström, Rasmus, Greber, Thomas, Büchner, Bernd, Avdoshenko, Stanislav M., Popov, Alexey A.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7065109/ https://www.ncbi.nlm.nih.gov/pubmed/31774196 http://dx.doi.org/10.1002/chem.201904879

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